So far only the odd eccentric has taken to using old chip fat as fuel. A messy process of filtering and the need to go begging to chip shops probably stop many people from pursuing this route to alternatively fuelling their cars. But now, researchers at the University of Leeds may have found a way to make this smelly fuel clean and pure.
Scientists at the university have found a new way to produce hydrogen fuel from the waste product. The new method promises to be cleaner and require less energy input than conventional forms of hydrogen production too. According to the team behind the research, not only does the new process generate some of the energy needed to make the hydrogen gas itself, it is also essentially carbon-neutral.
Hydrogen, traditionally, is steam-reformed from fossil fossil fuels, like natural gas. This process requires high temperatures of around 800 degrees, making it inefficient, expensive and still means reliance on a fossil fuel source. Traditional forms of hydrogen production from more complex fuels like waste vegetable oil require even higher temperatures to allow the effective release of hydrogen molecules, making it an expensive and environmentally unsound process.
But now Dr Valerie Dupont and colleagues at the university have perfected a two-stage process that is essentially self-heating. To begin, a nickel catalyst is blasted with air to form nickel oxide – an ‘exothermic’ process that can raises the starting temperature of 650 degrees by another 200 degrees, reducing the energy needs to reach the correct temperature. The chip fat fuel and steam mixture then reacts with the hot nickel oxide to make hydrogen and carbon dioxide.
“We are working towards a vision of the hydrogen economy,” said Dr Valerie Dupont, who is leading the Leeds-based project. “Hydrogen -based fuel could potentially be used to run our cars or even drive larger scale power plants, generating the electricity we need to light our buildings, run our kettles and fridges, and power our computers. But hydrogen does not occur naturally, it has to be made. With this process, we can do that in a sustainable way by recycling waste materials, such as used cooking oil.”
The researchers also added a special ‘sorbent’ material to trap all the carbon dioxide produced, leaving them with pure hydrogen gas. This trick eliminated the greenhouse gas emissions and also forced the reaction to keep running, increasing the amount of hydrogen made.
The researchers have shown that the two-stage process works well in a small, test reactor. They now want to scale-up the trials and make larger volumes of hydrogen gas over longer periods of time.
“The beauty of this technology is that it can be operated at any scale. It is just as suitable for use at a filling station as at a small power plant,” Dr Dupont said. “If we could create more of our electricity locally using hydrogen-powered fuel cells, then we could cut the amount of energy lost during transmission down power lines.”
Details of the work will be published in the journal Bioresource Technology.
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