A new, more efficient process for storing and generating hydrogen to power cars has been invented by chemical engineers at Purdue University in Indiana.
The new process called hydrothermolysis, uses a powdered chemical called ammonia borane, which has one of the highest hydrogen contents of all solid materials. The new process combines hydrolysis and thermolysis, two hydrogen-generating processes that by themselves are less than practical for use within vehicles.
Ammonia borane contains 19.6 per cent hydrogen, a high weight percentage that means a relatively small quantity and volume of the material are needed to store large amounts of hydrogen.
In hydrolysis, water is combined with ammonia borane and the process requires a catalyst to generate hydrogen. This means that the system requires a catalyst to be carried around inside the car and periodically replaced. Meanwhile in thermolysis the material must be heated to more than 170 degrees Celsius, to release sufficient quantities of hydrogen; a very energy intensive method.
However, as fuel cells in cars operate at about 85 degrees Celsius, researchers at the university looked for a new method that would work at the same temperature as the fuel cells to reduce the energy requirements.
The researchers conducted experiments using a reactor vessel operating at the same temperature as fuel cells. The process requires maintaining the reactor at a pressure of less than 200 pounds per square inch, far lower than the 5,000 psi required for current hydrogen-powered test vehicles that use compressed hydrogen gas stored in tanks.
In some experiments, the researchers used water containing a form of hydrogen called deuterium. Using water containing deuterium instead of hydrogen enabled the researchers to trace how much hydrogen is generated from the hydrolysis reaction and how much from the thermolysis reaction, details critical to understanding the process.
At the optimum conditions, hydrogen from the hydrothermolysis approach amounted to about 14 per cent of the total weight of the ammonia borane and water used in the process. This is significantly higher than the hydrogen yields from other experimental systems reported in the scientific literature, Arvind Varma, Professor of Chemical Engineering at the University says.
"This is important because the U.S. Department of Energy has set a 2015 target of 5.5 weight per cent hydrogen for hydrogen storage systems, meaning available hydrogen should be at least 5.5 per cent of a system’s total weight," he said. "If you’re only yielding, say, 7 per cent hydrogen from the material, you’re not going to make this 5.5 per cent requirement once you consider the combined weight of the entire system, which includes the reactor, tubing, the ammonia borane, water, valves and other required equipment."
The researchers determined that a concentration of 77 per cent ammonia borane is ideal for maximum hydrogen yield using the new process.
The new combined production process also promises to harness waste heat from fuel cells to operate the hydrogen generation reactor.
The research has been funded by the U.S. Department of Energy by a grant through the Energy Center in Purdue’s Discovery Park.
Future work on hydrothermolysis will explore scaling up the reactor to the size required for a vehicle to drive 350 miles before refuelling. Additional research also is needed to develop recycling technologies for turning waste residues produced in the process back into ammonia borane.
The technology may also be used to produce hydrogen for fuel cells to recharge batteries in portable electronics, such as notebook computers, cell phones, personal digital assistants, digital cameras, handheld medical diagnostic devices and defibrillators.
"The recycling isn’t important for small-scale applications, such as portable electronics, but is needed before the process becomes practical for cars," Varma said.
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